Found the problem...

https://bugs.kde.org/show_bug.cgi?id=321706

The good news is that it's fixed already, you just need to get the 
version with the fix applied.

Brian Cluff

On 01/15/2014 02:17 AM, Derek Trotter wrote:
> delboy@ladmo:~/.local/share/applications$ ls -l mimeapps.list
> -rw-rw-r-- 1 delboy delboy 15740 Jan 15 02:06 mimeapps.list
>
> I went into system settings - file associations and added amarok to the
> list of files to play mp3 files and moved it to the bottom of the list.
> Next I checked mimeapps.list and found the following two lines.
>
>  From mimeapps.list
> audio/x-mp3=kde4-amarok.desktop
> audio/x-mpeg=kde4-amarok.desktop
>
> Then I went back to file associations and removed amarok from the list
> of files to play mp3 files.  I clicked on an mp3 file and vlc played
> it.  I went back to look at mimeapps.list and these two lines were still
> there.
>
> From mimeapps.list
> audio/x-mp3=kde4-amarok.desktop
> audio/x-mpeg=kde4-amarok.desktop

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